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Highlights: • The thermodynamic model for the cementitious system was successfully developed. • The chemical degradation of concrete was greatly affected by rainwater types. • Inorganic carbon species in rainwater reduced the chemical resistance of concrete. • The durability of concrete to rainwater decreased with increasing fly ash content. This study presents a long-term degradation behavior of fly ash blended concrete in a vault type low- and intermediate-level radioactive waste (LILW) repository by thermodynamic equilibrium calculations using PHREEQC combined with CEMDATA18 database. Since rainwater plays a predominant role as leachate for the concrete waste container in the repository, the effect of chemical properties of seasonal rainwater on the chemical degradation of concrete was analyzed. In addition, the impact of the blending with fly ash on the chemical degradation was evaluated through a gradual replacement of ordinary Portland cement (OPC) by fly ash. Regardless of the replacement level, autumn rainwater showed the greatest influence on the concrete degradation owing to the presence of inorganic carbon species, which induce the carbonation. The resistance of concrete to chemical degradation by rainwater was persistently reduced due to the decreasing formation of portlandite and calcium silicate hydrate (C-S-H) with increasing replacement level.

The present work proposes the Cs-137 recovery from Electric Arc Furnace Dusts (EAFD) by leaching, in order to reduce the volume of radioactive waste to be managed. Leaching tests were performed on different samples of EAFD contaminated with Cs-137. Two leaching methodologies were tested: dynamic and static using as medium distilled water and in some cases NaOH. The results indicate the possibility of recovering Cs-137 from EAFD using the dynamic method; however, the recovery efficiencies of Cs-137 depend on EAFD's chemical composition. The leachates of Cs-137 were quantitatively adsorbed on exchange resins, showing its great potential to isolate or contain the Cs-137 recovery from EAFD. This study shows the feasible to apply the dynamic leaching methodology to recover Cs-137 from EAFD and the use of ion exchange resins for the isolation of removed Cs-137. (authors)

Selective HCl dissolution of ilmenite components for obtaining Ti or titanium dioxide (TiO{sub 2}) has been highly recognized due to its advantages, greater environmental friendliness, and simplicity, compared to H{sub 2}SO{sub 4} and Cl{sub 2} methods. The effect of numerous parameters has been studied with the one-factor-at-a-time method. The present study aimed to evaluate the effect of key operation parameters, such as acid-to-solid ratio (A/S: 5 to 20 mL/g), reaction temperature (T: 70 °C to 100 °C), and acid concentration (A pct: 15 to 30 wt pct), on the dissolution of Fe in HCl solution with the minimum Ti losses to the leachate from its abundant, domestic, and low-cost mineral source (Kahnooj ilmenite concentrate) using central composite design–response surface methodology. After 90 minutes of leaching, the Ti/Fe (pct) in terms of dissolved amounts was selected as the process assessment response function. Based on the conducted experimental and statistical analysis, increasing the levels of parameters in the studied domain leads to an increase in Ti/Fe (pct), in the order of A pct > T > A/S. Two statistically significant mutual interactions between A/S-T and T-A pct, with 95 pct confidence level, were revealed for the first time in this study. The optimization strategy was set to the minimization of Ti/Fe (pct) by considering the objective of study and the selected response function. The A/S, T, and A pct were determined to be 5 mL/g, 70 °C, and 15 pct, respectively, for maximum impurity dissolution and minimum Ti loss to the leachate.

Industrial wastewater treatment at the Fernald Preserve, Ohio, Site has been ongoing since a uranium metals refinery was constructed there at the beginning of the Cold War in 1951. Initially, the primary purpose of treatment was to recover uranium for reuse. Later, when cleanup of the site was progressing in the 1990's, wastewater treatment efforts greatly expanded. Large treatment facilities were constructed to handle contaminated surface water, groundwater, remediation wastewater, and leachate from the on-site disposal facility. These new facilities were designed to reduce uranium concentration to meet the US Environmental Protection Agency (EPA) drinking water standard and not generate large quantities of contaminated waste. Anion-exchange resin was chosen as the treatment media. The centerpiece of these facilities was the Advanced Wastewater Treatment facility, which had a treatment capacity of 10,978 liters per minute (lpm) (2900 gallons per minute [gpm]). Forecasts estimated that with the exception of groundwater the site's remediation would be completed in 2006. In 2003, the US Department of Energy (DOE) Office of Environmental Management began negotiations with the EPA and Ohio Environmental Protection Agency to reduce wastewater treatment capacity at the Fernald Environmental Management Project. These negotiations resulted in the site's treatment capacity being reduced to 6814 lpm (1800 gpm) via the Converted Advanced Wastewater Treatment facility (CAWWT). By 2010, the uranium concentration in the groundwater being pumped had been reduced to the degree that only intermittent treatment for uranium removal was needed. As a result, the CAWWT was considerably oversized. Increased maintenance on the aging CAWWT equipment led the DOE Office of Legacy Management (LM) to commission an assessment of the facility, which was completed in early 2015. The condition assessment identified numerous components at or near the end of their design life. Based on the assessment's findings and the fact that the current facility's treatment capacity was substantially greater than needed, LM began looking at options for an appropriately sized treatment system to handle the site's needs until the groundwater remediation was completed (currently projected for 2039). Options were evaluated in the spring of 2015, and LM presented the recommended changes to regulators and stakeholders. Approvals for a new, smaller system with a 189 lpm (50 gpm) capacity were obtained through a series of meetings in the summer of 2015. After more detailed planning in the fall of 2015, LM initiated the project in 2016. The project comprises the following four phases: (1) Removal and disposal of used media, piping, and tanks to make room for the new system in the existing building (completed in January 2017); (2) design of the new system (completed in April 2017); (3) construction, installation, and startup of the new system (completed in May 2018); and (4) backwash basin refurbishment (yet to be completed). In the late 2030's, when groundwater remediation is projected to be completed at the site, it is anticipated that the only remaining wastewater treatment need will be for small quantities of leachate from the on-site disposal facility. Results of leachate treatment testing in 2003 indicate it may be feasible to utilize a small passive treatment system for this leachate. (authors)

URS-CH2M Oak Ridge LLC (UCOR) manages the cleanup of the 2,200-acre East Tennessee Technology Park (ETTP) for its client, the U.S. Department of Energy (DOE), in Oak Ridge, Tennessee. The ETTP site was contaminated with radioactive, hazardous and industrial wastes generated by more than 40 years of national defense and energy missions. Stormwater management is a critical activity at the DoE's Oak Ridge Reservation Environmental Management Waste Management Facility (EMWMF) due to the high average rainfall and the consequences if inadequately managed. EMWMF is located in East Tennessee with an average rainfall of 54.25 inches/year. EMWMF has implemented a successful, multipart strategy to maximize the margin of safety, reduce the volume of stormwater requiring management, and otherwise minimize operational impacts from large volumes of landfill water. The strategy consists of: - Pre-planning and preparation; - Landfill storm water prevention; - Inventory minimization; - Accelerated storm water removal. Since implementation of this aggressive water management strategy in 2017, EMWMF has reduced the volume of leachate requiring management by approximately 27%. This reduction increased the safety and compliance for the EMWMF, while at the same time, reduced costs. (authors)

URS-CH2M Oak Ridge LLC (UCOR) manages the cleanup of the 2,200-acre East Tennessee Technology Park (ETTP) for its client, the U.S. Department of Energy (DOE), in Oak Ridge, Tennessee. The ETTP was contaminated with radioactive, hazardous and industrial wastes generated by more than 40 years of national defense and energy missions. In disposing of low-level radioactive and other wastes from demolition activities, the UCOR approach relies on the availability of onsite facilities to streamline disposal, reduce costs and enhance cleanup schedules while confining shipments and related hazards onsite. The sanitary/industrial waste facility, known as the Oak Ridge Reservation Landfill Facility (ORRLF) is a solid waste operation that receives and disposes of sanitary/industrial, construction/demolition and classified, special waste; and spoil materials types of waste generated at the U.S. Department of Energy (DOE) Oak Ridge facilities. ETTP is the primary generator; however, the landfill accepts waste from Y-12 National Security Complex (Y-12), Oak Ridge National Laboratory and other DOE prime contractors in the Oak Ridge area. ORRLF's mission is to receive nonhazardous, non-radioactive, and non-Resource Conservation and Recovery Act of 1976 (RCRA)-regulated solid wastes. Approved operations include receiving, compacting, and covering wastes; leachate management, site drainage; erosion control and prevention, inspections, maintenance and recording keeping. The Oak Ridge Reservation has three separate State of Tennessee-permitted active landfills (Landfill IV, Landfill V, and Landfill VII) that meet different disposal needs -- classified industrial waste, industrial waste that includes office trash and cafeteria waste, and construction and demolition debris,. As with a typical landfill, strategic waste placement and covering involves moving a lot of soil, usually resulting in large areas of exposed land. After increased sediment was noted in streams following heavy rains, a concerted erosion prevention and sediment control effort began in 2017. While not uncommon for landfills, the ORRLF staff knew they could do better in controlling sediment. In response, the ORRLF staff developed an approach of aggressive revegetation, ditch improvements and other erosion controls. Staff developed a list of all the areas that needed the most attention and requested resources. UCOR management arranged funding for needed improvements. The oldest of the three landfills is Industrial Landfill IV, which opened in 1989 and has an expected remaining 60 years of life. Therefore, how the landfills are maintained/managed today directly affects the compliance posture, the capacity, and the infrastructure in the future. A systematic, aggressive and multi-pronged approach was taken to address the major concerns first, then continue with longer-term, and/or lower priority projects. Buy-in was obtained from both craft and supervision, resulting in approaches like 'Ditch of the Month'. In addition, management support at the highest levels has provided resources and recognition that further fuels progress. After working on the site for the past year, what used to be exposed brown hills looks more like a golf course now. Now that the grass is established and other erosion controls are in place, the amount of sediment leaving the site has been reduced, and the appearance of the landfills is improved. Vegetation dissipates the kinetic energy from rain droplets while the root system helps hold the soil in place, and wire-reinforced silt fences and straw wattles have greatly improved erosion control. Improved ditches reduce the runoff velocities allowing sediments to fall out of suspension in the stormwater before they reach the receiving waters, and structures are in place to let finer sediment settle in ponds rather than going downstream. In addition, the project has added more stone to roadways to minimize tracking dirt down the road as an average of 20 to 40 trucks per day enter and leave the site. Ongoing landfill erosion and sediment control must be funded and maintained continually. The lack of attention to either resource will negatively affect the condition of the landfill fairly quickly. Constant compliance commitment is necessary to ensure protection to the environment, the operator/workers and the public. Operations must include sediment control, pond maintenance and clean out, road maintenance and construction, erosion prevention, seeps repair, leachate management, landfill expansion, mowing and grounds upkeep and much more. Knowledgeable/experience staff is also crucial. Knowing how to build lifts, create leachate drainage windows, respond to high rains events, compact waste will impact operations today and future operations into the closure / post closure periods. (author)

Canadian Nuclear Laboratories plans to construct an engineered containment mound (ECM) at its Chalk River Laboratories site in Ontario for safe management of radioactive and mixed waste at the facility. The ECM is designed for containment of 1,000,000 cubic meters of waste, and will be operated over a period of 50 years. Contact storm water, leachate, and other wastewater will be generated during operation of the ECM, and must be treated prior to discharge to the environment. The wastewater is projected to contain low concentrations of radionuclides and metals, as well as other cations and anions, and low concentrations of organic chemicals. Through comparison with surface water discharge criteria, radionuclides cesium-137 and strontium-90, and metals including aluminum, barium, copper, iron, lead, and manganese were projected to be present in the wastewater at concentrations that may exceed surface water discharge criteria, and were therefore targeted for treatment. Several technologies, including chemical precipitation, membrane filtration, ion exchange, and reverse osmosis were reviewed and tested on a laboratory scale using simulated wastewater prepared to replicate the concentrations of both target and non-target constituents. Based upon the results of the laboratory-scale tests, a six-week pilot test was conducted to simulate the performance of the technologies under continuous-flow conditions and determine full-scale design criteria. This paper describes the methodology and results of the six-week pilot test, and how the test results were used to inform the full-scale wastewater treatment system design. (authors)

Canadian Nuclear Laboratories (CNL) proposes to develop a Near Surface Disposal Facility (NSDF) at the Chalk River Laboratories (CRL) site in Ontario, Canada for disposal of CNL's Low Level Radioactive Waste (LLW) and other suitable wastes meeting the Waste Acceptance Criteria (WAC). The NSDF's Engineered Containment Mound (ECM) includes base liner and final cover systems. These liner systems are designed to perform effectively for a total of 550 years. The specified geomembrane in the NSDF detailed design is 2 mm thick High Density Polyethylene Geomembrane (HDPE GMB) double sided textured and white surface. CNL's approach to collaborate with Subject Matter Expert (SME) consultants and contractors, a Canadian university, and industry has enabled the NSDF to incorporate current best design practices, particularly for the design of the ECM's liner systems. This paper describes the HDPE GMB testing program and how the results of the state-of-the-art research have been utilized in the design of the NSDF's liner system and in selection of the best candidate materials to strengthen the confidence that the required service-life will be met. The testing program includes index properties and long-term performance evaluation tests of the five candidate HDPE GMBs using leachate simulant comparable to expected NSDF leachate and an index simulant used for testing many GMBs. The results of the tests are used as the basis to assess expected HDPE GMBs long-term performance. The expected long-term performance is applied as the key consideration for the final selection of the HDPE GMB in the NSDF project. Preliminary results of the testing program indicate that an expected service-life of 550 years will likely be met by the candidate HDPE GMB. (authors)

Vegetable and fruit waste (VFW) is becoming a heavy burden of municipal waste disposal because of its huge amount, but it is a potentially valuable resource that can be developed into high value products such as methane. Conventional anaerobic digestion processes are not suitable for solving the problem of easy acidification of VFW. Thus, a two-stage laboratory-scale anaerobic digestion system was assembled for waste reduction and biogas production of VFW in the mesophilic temperatures. The biphasic system consists of a 70-L leach bed reactor (LBR) and a 35-L continuous stirred tank reactor (CSTR). Water is sprinkled over the material to enhance the extraction process of acidification phase. The leachate was then transferred to the CSTR for biogas production. Batch digestion was lasted 120 h until no biogas was produced. Leachate with a volatile fatty acid (VFA) concentration of 7.6 g/L was obtained within 10 h. The results showed that overall 70.9% of the volatile solids (VS) was removed in the solid-phase system. Over 90% of VFAs were reduced in the methanogenic reactor, and it has been observed that the maximum biogas production rate was 51.26 mL/(d gVS). The maximum methane concentration in the produced biogas was 71%.

Remediation of cadmium (Cd) from contaminated soils is considered a complicated task of environmental safety. A column leaching experiment was planned to estimate the influence of biochar (BC), zeolite (ZE) and steel slag (SL) at 1.5% and 3% application rate on Cd leaching behavior and chemical fractionation in contaminated soil. A sequential extraction procedure, the European Community Bureau of Reference (BCR), Toxicity Characteristic Leaching Procedure (TCLP) and NH{sub 4}NO{sub 3} were performed after leaching was completed. The soluble portion of Cd was decreased by 36.3%, 18.4% and 28.7% and Cd contents in leachate were decreased by 44.8%, 30% and 31.3% after BC, ZE and SL addition at 3% rate, respectively over control soil. The greater reduction in TCLP extractable Cd was observed by 29.6% with BC and 22.4% with ZE and 25.7% with SL at 3% application rate. Overall, biochar can be considered an efficient soil amendment to reduce Cd leaching as well as increased its stabilization within soil profile.